مروری بر فرآیند گوگردزدایی جذبی از فرآورده‌های نفتی توسط جاذب‌های متخلخل کربنی

نوع مقاله : مروری

نویسندگان

1 دانشجوی کارشناسی ارشد، مرکز تحقیقات کربن سبز، دانشکده مهندسی شیمی، دانشگاه صنعتی سهند، تبریز، ایران

2 دکتری/استادیار، مرکز تحقیقات کربن سبز، دانشکده مهندسی شیمی، دانشگاه صنعتی سهند، تبریز، ایران

چکیده

امروزه مشکلات فرایند گوگردزدایی هیدروژنی، منجر به  توسعه روش‌های نوین همچون گوگردزدایی جذبی (ADS)، استخراجی، اکسیداسیونی و... شده است برخلاف روش گوگردزدایی هیدروژنی، ADS بدون نیاز به هیدروژن گران‌قیمت و پرخطر و در شرایط عملیاتی (دما و فشار) پایین توانایی حذف ترکیب‌های گوگردی مقاوم نظیر DBT و مشتقات آن را دارد. در این مقاله، علاوه بر مقایسه روش‌های نوین گوگردزدایی، از بین جاذب‌های جامد مورد استفاده در فرایند ADS، به بررسی عملکرد  جاذب‌های متخلخل کربنی،  به دلیل  داشتن ویژگی‌های منحصربه‌فرد آن‌ها نظیر مساحت سطح و تخلخل زیاد، اصلاح آسان خواص فیزیکی - شیمیایی و هزینه تمام شده مقرون‌به‌صرفه و... پرداخته شده است. همچنین، برای درک بهتر فرایند، پارامترهای مؤثر فرایندی، سینتیک و ترمودینامیک و انواع مکانیسم‌های جذب در فرایند ADS توسط مواد کربنی بررسی و تحلیل شده است و نهایتاً، انواع روش‌های بازیابی جاذب‌های کربنی معرفی و چالش‌های پیشروی فرایند ADS اشاره شده است.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Review on Adsorptive Desulfurization of Petroleum Products by Porous Carbon Adsorbents

نویسندگان [English]

  • Ramin Sayyar 1
  • Reza Khoshbouy 2
1 M.Sc. Student, Green Carbon Research Center, Chemical Engineering Faculty, Sahand University of Technology, Tabriz, Iran
2 Assistant Professor, Green Carbon Research Center, Chemical Engineering Faculty, Sahand University of Technology, Tabriz, Iran
چکیده [English]

Today, the drawbacks of the hydrodesulfurization process have led to the development of new methods such as adsorptive desulfurization (ADS), extraction, oxidation, etc. Unlike the hydrodesulfurization method, ADS has the ability to remove resistant sulfur compounds such as DBT and its derivatives without the need for expensive and risky hydrogen and under low operating conditions (temperature and pressure). In this article, in addition to the comparison of modern desulfurization methods, among the solid adsorbents used in the ADS process, the performance of porous carbon adsorbents is investigated due to their unique characteristics such as high surface area and porosity, easy modification of physical-chemical properties and the cost is affordable and has been paid. Also, for a better understanding of the process, the effective process parameters, kinetics and thermodynamics and various adsorption mechanisms in the ADS process by carbon materials have been investigated. And finally, various methods of recovery of carbon adsorbents are introduced and the challenges of advancing the ADS process are mentioned.

کلیدواژه‌ها [English]

  • Desulfurization Methods
  • Adsorptive Desulfurization
  • Porous Carbon Materials
  • Petroleum products
  • Adsorption Mechanism

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